Title of article
Pronounced rate enhancements in condensation reactions attributed to the fluorous tag in modified Mukaiyama reagents
Author/Authors
Matsugi، نويسنده , , Masato and Nakamura، نويسنده , , Shuichi and Kunda، نويسنده , , Yoko and Sugiyama، نويسنده , , Yuya and Shioiri، نويسنده , , Takayuki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
133
To page
135
Abstract
The observed rate enhancement for the condensation reaction between 2-phenyl benzoic acid and isopropanol mediated by fluorous Mukaiyama reagents is described. It is shown that Mukaiyama reagents bearing a fluorous tag increase the reaction rate considerably when compared to their non-fluorous tagged counterpart. Furthermore, it is observed that the longer the fluorous chain, the higher the activity of the Mukaiyama reagent.
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1870515
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