Title of article :
The first ‘alkane-like’ functionalization of n-alkyl acetates: a new method for one-pot selective syntheses of bifunctional aliphatic compounds with an acetate group
Author/Authors :
Orlinkov، نويسنده , , Alexander V. and Kagramanov، نويسنده , , Nikolai D. and Petrovskii، نويسنده , , Pavel V. and Akhrem، نويسنده , , Irena S. and Avetisyan، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
Selective one-pot functionalization of linear alkyl acetates CnH2n + 1OCOMe (n = 6, 8), with CO and various nucleophilic substrates (iso-propanol, morpholine, piperidine, and anisole) in the presence of the superelectrophilic system CBr4·2AlBr3 is performed for the first time.
Keywords :
Superelectrophiles , Functionalized alkyl acetates , Functionalization , n-Alkyl acetates
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters