Author/Authors :
Matsumoto، نويسنده , , Yasumasa and Selim، نويسنده , , Khalid B. and Nakanishi، نويسنده , , Hirotsugu and Yamada، نويسنده , , Kenichi and Yamamoto، نويسنده , , Yasutomo and Tomioka، نويسنده , , Kiyoshi، نويسنده ,
Abstract :
Chiral C2-symmetric N-heterocyclic carbenes (NHCs) were tested for their stereocontrolling abilities in gold(I)-catalyzed asymmetric cyclization of 1,6-enynes giving the corresponding cyclopentane derivatives with moderate enantioselectivity of up to 59%.