Author/Authors :
Naumov، نويسنده , , Roman N. and Kozlov، نويسنده , , Artem V. and Kanunnikov، نويسنده , , Kirill B. and Gَmez-Ruiz، نويسنده , , Santiago and Hey-Hawkins، نويسنده , , Evamarie and Latypov، نويسنده , , Shamil K. and Karasik، نويسنده , , Andrey A. and Sinyashin، نويسنده , , Oleg G.، نويسنده ,
Abstract :
The rac stereoisomer of a novel cryptand containing two bridgehead nitrogen and four asymmetric phosphorus atoms in the 16-membered core cycle was obtained stereoselectively via the reaction of bis(mesitylphosphino)propane, formaldehyde, and meta-xylylenediamine in the course of a covalent self-assembly process.
Keywords :
stereoselectivity , Phosphorus-containing cryptand , SELF-ASSEMBLY , True racemate
