Title of article :
A novel method for the reduction of alkenes using the system silane/oxo-rhenium complexes
Author/Authors :
de Noronha، نويسنده , , Rita G. and Romمo، نويسنده , , Carlos C. and Fernandes، نويسنده , , Ana C.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
In this work, we report the first practical application of high-valent oxo-complexes for the reduction of alkenes to the corresponding alkanes. The catalytic system Ph(Me)2SiH/ReIO2(PPh3)2 (5 mol %) proved to be very efficient for the reduction of mono- and disubstituted alkenes under solvent-free conditions.
Keywords :
alkenes , Reduction , Oxo-rhenium complexes , Silanes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
