Title of article :
Chemoselective SN2′ reaction of nitroalkanes to dialkyl 2-(bromomethyl)fumarates under cetyltrimethylammonium hydroxide (CTAOH) catalysis
Author/Authors :
Ballini، نويسنده , , Roberto and Gabrielli، نويسنده , , Serena and Palmieri، نويسنده , , Alessandro، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
The chemoselective SN2′ reaction of a variety of primary nitroalkanes to dialkyl 2-(bromomethyl)fumarates can be efficiently performed under cetyltrimethylammonium hydroxide (CTAOH) catalysis. The α,β-unsaturated esters were obtained in satisfactory to good yields with the complete retention of the nitro group.
Keywords :
Nitroalkanes , CTAOH , Chemoselective SN2? reaction , ? , ?-Lactame , ?-unsaturated esters
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
