Title of article :
The generation of diazirinone: a computational study
Author/Authors :
Moss، نويسنده , , Robert A. and Sauers، نويسنده , , Ronald R.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
Computational studies indicate that the reaction of p-nitrophenoxyfluorodiazirine with fluoride ion should generate diazirinone. However, fluoride ion also catalyzes the decomposition of diazirinone to carbon monoxide and nitrogen, so that the diazirinone is likely to be unstable to the conditions used to generate it.
Keywords :
fluoride ion , Calculations , Catalysis , Diazirines
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters