Title of article
Chelation-assisted palladium-catalyzed acyloxylation of benzyl sp3 C–H bonds using PhI(OAc)2 as oxidant
Author/Authors
Zhang، نويسنده , , Shouhui and Luo، نويسنده , , Fang and Wang، نويسنده , , Wenhui and Jia، نويسنده , , Xiaofei and Hu، نويسنده , , Maolin and Cheng، نويسنده , , Jiang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
3317
To page
3319
Abstract
A chelation-assisted palladium-catalyzed acyloxylation of the sp3 C–H bond of benzyl by carboxylic acid is described, which employs PhI(OAc)2 as a stoichiometric oxidant. The procedure tolerates a series of functional groups, such as methoxyl, chloro, bromo, iodo, vinyl, formyl, phenolic hydroxyl, nitro, and cyano groups, providing the acyloxylation products in moderate to good yields.
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1872432
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