DMAP-catalyzed cyanation of aldehydes and ketones with ethyl cyanoformate
Author/Authors :
Aoki، نويسنده , , Shohei and Kotani، نويسنده , , Shunsuke and Sugiura، نويسنده , , Masaharu and Nakajima، نويسنده , , Makoto، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Pages :
3
From page :
3547
To page :
3549
Abstract :
The cyanation of carbonyl compounds with ethyl cyanoformate is catalyzed by 4-dimethylaminopyridine (DMAP) to afford the corresponding cyanohydrin carbonates in excellent yields. The system provides a convenient method for cyanation of carbonyl compounds without using metal catalysts or solvents.