Title of article
Selective preparation of terminal alkenes from aliphatic carboxylic acids by a palladium-catalysed decarbonylation–elimination reaction
Author/Authors
Jérôme Le Nôtre، نويسنده , , Jérôme and Scott، نويسنده , , Elinor L. and Franssen، نويسنده , , Maurice C.R. and Sanders، نويسنده , , Johan P.M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
3712
To page
3715
Abstract
Trialkylamines were used as additives in the decarbonylation–elimination reaction catalysed by the combination of palladium(II) chloride and DPE-Phos. Aliphatic carboxylic acids were transformed at relatively low temperature into terminal alkenes in high yield and high selectivity, without the need for distillation, thereby avoiding isomerisation.
Keywords
Terminal alkenes , fatty acids , PALLADIUM , Decarbonylation
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1873474
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