Author/Authors :
Chen، نويسنده , , Weiliang and Hui، نويسنده , , Yonghai and Zhou، نويسنده , , Xin and Jiang، نويسنده , , Jun and Cai، نويسنده , , Yunfei and Liu، نويسنده , , Xiaohua and Lin، نويسنده , , Lili and Feng، نويسنده , , Xiaoming، نويسنده ,
Abstract :
Chiral N,N′-dioxide-Ytterbium(III) complexes promoted the asymmetric addition of diethyl phosphate to aldehydes, giving the corresponding products with good yields and enantioselectivities. The addition of pyridine favored both reactivity and enantioselectivity. A possible catalytic cycle was proposed to explain the mechanism of the asymmetric hydrophosphonylation of aldehydes.
Keywords :
N?-Dioxides , Ytterbium , Hydroxy phosphonates , Asymmetric hydrophosphonylation , Aldehydes , N
