Title of article
Metal-free oxidative C–C bond formation of active methylenic sp3 C–H bonds with benzylic sp3 C–H and allylic sp3 C–H bonds mediated by DDQ
Author/Authors
Ramesh، نويسنده , , D. and Ramulu، نويسنده , , U. and Rajaram، نويسنده , , S. and Prabhakar، نويسنده , , P. and Venkateswarlu، نويسنده , , Y.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
6
From page
4898
To page
4903
Abstract
An efficient and simple method for the oxidative coupling of benzylic and allylic sp3 C–H bonds with active methylenic sp3 C–H bonds under metal-free conditions was developed by employing 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) as an oxidant. The reaction was shown to proceed smoothly for various 1,3-dicarbonyl compounds with a range of benzylic and allylic substrates in good to excellent yields.
Keywords
Metal-free , oxidative coupling , DDQ , C–C bond formation , 1 , 3-dicarbonyl
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1874541
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