Title of article
Dual mechanisms of an organocatalytic homodimerization reaction
Author/Authors
Guidi، نويسنده , , Vanina and Sandoval، نويسنده , , Sergio and McGregor، نويسنده , , Michael A. and Rosen، نويسنده , , William، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
5
From page
5086
To page
5090
Abstract
The l-proline organocatalytic homodimerization of 2-cyclohexenone has been studied and it is concluded that the mechanism of the reaction follows competing pathways involving either a two-step imine/enamine addition or a concerted Diels–Alder cycloaddition where the ultimate product distribution is dependent upon the ratio of the organocatalyst to 2-cyclohexenone and a base present.
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1874713
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