Title of article
Copper(I) thiophenolate in copper N-heterocyclic carbene preparation
Author/Authors
Federico Cisnetti، نويسنده , , Federico and Lemoine، نويسنده , , Pascale and El-Ghozzi، نويسنده , , Malika and Avignant، نويسنده , , Daniel and Gautier، نويسنده , , Arnaud، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
5226
To page
5229
Abstract
Copper(I) thiophenolate was considered as a copper source for the synthesis of Cu(I)-N-heterocyclic carbenes (Cu(I)-NHCs). It displayed a dual mode of reactivity allowing the synthesis of both thiophenolato-Cu(I)-NHCs via the free carbene in a one-pot procedure starting from imidazolium chlorides and chloro-Cu(I)-NHCs by a salt metathesis reaction starting from chloro-Ag(I)-NHCs.
Keywords
Transmetallation , Copper , Thiophenolate , N-Heterocyclic carbenes
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1874830
Link To Document