Author/Authors :
Srihari، نويسنده , , P. and Kumaraswamy، نويسنده , , B. and Shankar، نويسنده , , P. and Ravishashidhar، نويسنده , , V. and Yadav، نويسنده , , J.S.، نويسنده ,
Abstract :
The stereoselective total synthesis of achaetolide 1 has been achieved and its absolute stereochemistry has been reconfirmed to be 3S,6R,7S,9R configuration. Keck allylation, Sharpless asymmetric dihydroxylation, and ring closing metathesis are the key steps involved in the target synthesis.
