Title of article
Binary 1,4-asymmetric induction toward imines from a single allyltin reagent with a chiral oxygen functional group
Author/Authors
Nishigaichi، نويسنده , , Yutaka and Fujimoto، نويسنده , , Takahiro and Takuwa، نويسنده , , Akio and Iwamoto، نويسنده , , Hidetoshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
6298
To page
6300
Abstract
A single allyltin reagent possessing a chiral oxygen functional group afforded each diastereomeric product in the reaction with N-sulfonylimines promoted by appropriate Lewis acids in a binary stereoselective manner. InCl3 selectively provided the syn-1,4-amino alcohol derivatives, while BF3 and TiCl4 gave the anti-products preferentially.
Keywords
4-Aminoalcohol derivatives , Asymmetric induction , 1 , Lewis acid , sulfonylimine , allyltin
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1875701
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