Title of article :
Tellurium in organic synthesis: a new approach to trisubstituted γ-butyrolactones with trans–trans relative stereochemistry. Total enantioselective synthesis of (−)-Blastmycinolactol, (+)-Blastmycinone, (−)-NFX-2, and (+)-Antimycinone
Author/Authors :
Ferrarini، نويسنده , , Renan S. and Dos Santos، نويسنده , , Alcindo A. and Comasseto، نويسنده , , Joمo V.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
The total synthesis of (−)-Blastmycinolactol, (+)-Blastmycinone, (−)-NFX-2, and (+)-Antimycinone was accomplished in few steps in high yields and ee, starting from enantiomerically enriched (S)-Z-vinylic hydroxytellurides.
Keywords :
(?)-NFX-2 , (+)-Blastmycinone , Te/Li exchange reaction , (+)-Antimycinone , (?)-Blastmycinolactol , ?-butyrolactones
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters