Title of article :
Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor
Author/Authors :
Yavorskyy، نويسنده , , Alexander and Shvydkiv، نويسنده , , Oksana and Nolan، نويسنده , , Kieran and Hoffmann، نويسنده , , Norbert and Oelgemِller، نويسنده , , Michael، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
A novel continuous-flow photoreactor with parallel capillaries was constructed and successfully tested for the DMBP-sensitized addition of isopropanol to furanones. Complete conversions were achieved after a maximum of 10 min of irradiation with a single 350 nm lamp. The results were compared to analogous batch experiments using a conventional Rayonet chamber reactor equipped with 16 UVA lamps. The capillary tower generally showed higher space-time yields.
Keywords :
Photoaddition , furanones , photochemistry , Microreactor , Microcapillary , Continuous-flow synthesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters