Title of article :
Base-free oxidation of thiols to disulfides using selenium ionic liquid
Author/Authors :
Thurow، نويسنده , , Samuel and Pereira، نويسنده , , Vanda A. and Martinez، نويسنده , , Débora M. and Alves، نويسنده , , Diego and Perin، نويسنده , , Gelson and Jacob، نويسنده , , Raquel G. and Lenardمo، نويسنده , , Eder J.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Pages :
4
From page :
640
To page :
643
Abstract :
We present here the results on the use of 1-n-butyl-3-methylimidazolium methylselenite, [bmim][SeO2(OCH3)], in the synthesis of symmetrical disulfides starting from thiols. This efficient and improved method is general for aromatic, aliphatic, and functionalized thiols affording the disulfides in good to excellent yields after easy work up. The use of a microwave accelerates the reaction and the [bmim][SeO2(OCH3)] was reused for further oxidation reactions.
Keywords :
Selenium ionic liquid , disulfides , Oxidation
Journal title :
Tetrahedron Letters
Serial Year :
2011
Journal title :
Tetrahedron Letters
Record number :
1876712
Link To Document :
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