Title of article
Sequential oxidation/asymmetric aldol reaction of primary alcohols by resin-supported catalysts
Author/Authors
Akagawa، نويسنده , , Kengo and Takigawa، نويسنده , , Shota and Mano، نويسنده , , Erika and Kudo، نويسنده , , Kazuaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
770
To page
773
Abstract
The sequential reaction including alcohol oxidation by TEMPO/Cu system and the asymmetric aldol reaction by peptide catalysis was realized using resin-supported catalysts. The step of oxidizing primary alcohols to the corresponding aldehydes could be dramatically enhanced through the introduction of triglycyl peptide to supported TEMPO and the method of pre-adsorbing a Cu-complex into resin beads.
Keywords
Sequential reaction , Asymmetric aldol reaction , TEMPO oxidation , Peptide catalyst , Resin-supported catalyst
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1876818
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