Author/Authors :
Nobuta، نويسنده , , Tomoya and Tada، نويسنده , , Norihiro and Hattori، نويسنده , , Kasumi and Hirashima، نويسنده , , Shin-ichi and Miura، نويسنده , , Tsuyoshi and Itoh، نويسنده , , Akichika، نويسنده ,
Abstract :
We report a useful method for facile aerobic photo-oxidative synthesis of α-diketones from alkynes with MgBr2·OEt2. This procedure provides a practical synthetic method of α-diketones using easily handled bromine sources, harmless visible light, and molecular oxygen as terminal oxidant.
Keywords :
Alkynes , Photo-oxidation , MgBr2·OEt2 , ?-diketones , Aerobic