Title of article :
Nucleophilic allylation of N,O-acetals with allylic alcohols promoted by Pd/Et3B and Pd/Et2Zn systems
Author/Authors :
Yamaguchi، نويسنده , , Yumi and Hashimoto، نويسنده , , Mariko and Tohyama، نويسنده , , Katsumi and Kimura، نويسنده , , Masanari، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
Pd/Et3B and Pd/Et2Zn systems promote the nucleophilic allylations of 2-aminotetrahydrofuran and 2-aminotetrahydropyran with allylic alcohols to provide ω-hydroxyhomoallylamines in high yields. The transformation is applicable to the allylation of non-protective carbohydrates, such as ribose and deoxyribose.
Keywords :
allylation , carbohydrate , PALLADIUM , Hemiacetal , umpolung
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
