Title of article :
Samarium diiodide mediated intramolecular cyclisation of mixed enone–enoate systems: a simple preparation of spirocyclic ethers
Author/Authors :
Meng، نويسنده , , Junxiu and Light، نويسنده , , Mark E. and Kilburn، نويسنده , , Jeremy D. and Dixon، نويسنده , , Sally، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
Samarium(II) diiodide mediated intramolecular cyclisation of mixed enone–enoate substrates in THF/MeOH is described. Spirocyclic ethers are obtained, and the stereodefined preparation of 1-oxaspiro[4.4]nonan-7-one products is included.
Keywords :
samarium(II) diiodide , Reductive cyclisation , spirocycle , Michael addition , Chelation control
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
