Title of article :
Palladium catalyzed N-alkylation of amines with alcohols
Author/Authors :
Zhang، نويسنده , , Yan and Qi، نويسنده , , Xiujuan and Cui، نويسنده , , Xinjiang and Shi، نويسنده , , Feng and Deng، نويسنده , , Youquan، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
An iron oxide immobilized palladium catalyst was prepared for the N-alkylation of amines with alcohols under base and organic ligand free conditions. Applying the optimized reaction conditions, the coupling reactions of amines and alcohols with various structures could be realized with up to 99% isolated yields. The catalysts were studied by XRD, BET, and XPS and the mechanism was studied by DFT calculations.
Keywords :
PALLADIUM , Alkylation , alcohol , Amine
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters