Title of article
Iridium-catalyzed asymmetric hydrogenation of imines in supercritical carbon dioxide using phosphite-type ligands
Author/Authors
Lyubimov، نويسنده , , Sergey E. and Rastorguev، نويسنده , , Eugenie A. and Petrovskii، نويسنده , , Pavel V. and Kelbysheva، نويسنده , , Elena S. and Loim، نويسنده , , Nikolay M. and Davankov، نويسنده , , Vadim A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
1395
To page
1397
Abstract
A series of chiral phosphite-type ligands has been evaluated in the iridium-catalyzed asymmetric hydrogenation of acyclic arylimines in supercritical CO2. High reactivities (100% conversion in 50–120 min) and enantioselectivities (up to 95%) were obtained.
Keywords
Enantioselective hydrogenation , Supercritical carbon dioxide , imines , iridium
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877312
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