Title of article :
A sustainable procedure for highly enantioselective organocatalyzed Diels–Alder cycloadditions in homogeneous ionic liquid/water phase
Author/Authors :
De Nino، نويسنده , , Antonio and Bortolini، نويسنده , , Olga and Maiuolo، نويسنده , , Loredana and Garofalo، نويسنده , , Angelo and Russo، نويسنده , , Beatrice and Sindona، نويسنده , , Giovanni، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
The MacMillan iminium catalyst was investigated for asymmetric Diels–Alder cycloadditions in ionic liquid/H2O homogeneous phase. Superior selectivity, product yield, and shorter reaction times were observed in comparison with classical organic solvents. Additional advantages are the easy synthetic procedure, the excellent recovery of products, and the recyclability of the whole system.
Keywords :
recyclability , organocatalyst , Diels–Alder reaction , Ionic liquid
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters