Title of article
An improved procedure for the preparation of β-thiohydroximates for glucosinolate synthesis
Author/Authors
Cobb، نويسنده , , Susan E. and Morgan، نويسنده , , Kate F. and Botting، نويسنده , , Nigel P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
1605
To page
1607
Abstract
A novel and simple method is described for the synthesis of β-thiohydroximates from oximes and 2,3,4,6-tetra-O-acetyl-1-thio-β-d-glucopyranose, which are key intermediates in the synthesis of glucosinolates. The procedure involves the in situ formation of an oximyl chloride from the oxime, using inexpensive bleach, which is then reacted directly under basic conditions with the thioglucopyranose.
Keywords
glucosinolate , nitrile oxide , Thiohydroximate , Thioglucose , Oximyl chloride
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877477
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