Title of article :
Solvent-induced hydrogen tunnelling in ascorbate proton-coupled electron transfers
Author/Authors :
Karkovi?، نويسنده , , Ana and Brala، نويسنده , , Cvijeta Jakobu?i? and Pilepi?، نويسنده , , Viktor and Ur?i?، نويسنده , , Stanko، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
The over-the-barrier proton-coupled electron transfer interaction of an ascorbate monoanion with a hexacyanoferrate(III) ion in water entered into a tunnelling regime in water–1,4-dioxane, water–ethanol and water–acetonitrile mixed solvents.
Keywords :
Proton-coupled electron transfer , kinetic isotope effect , Hydrogen tunnelling , Dynamics , Ascorbate , solvent
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
