Title of article
Stereoselective synthesis of the decahydrofluorene core of the hirsutellones
Author/Authors
Halvorsen، نويسنده , , Geoff T. and Roush، نويسنده , , William R.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
2072
To page
2075
Abstract
A stereoselective synthesis of the decahydrofluorene core of the hirsutellones was accomplished in eight steps and in 43% overall yield. The key step of the synthesis is the highly stereoselective intramolecular Diels–Alder cyclization of the siloxacyclopentene-constrained tetraene 1.
Keywords
Hirsutellone B , intramolecular Diels–Alder reaction , Siloxacyclopentene-constrained dienophile , stereoselective synthesis , Oxonium ion activated dienophile
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877793
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