Title of article :
Stereoselective total synthesis of cryptopyranmoscatone A1
Author/Authors :
Sabitha، نويسنده , , Gowravaram and Reddy، نويسنده , , S. Siva Sankara and Yadav، نويسنده , , J.S.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
The first total synthesis of cryptopyranmoscatone A1 isolated from Cryptocarya moschata has been accomplished from 3,4,6-tri-O-acetyl-d-glucal. In addition to the RCM and cross-metathesis (CM) reactions, the synthesis features a highly diastereoselective Brown’s allylation reaction and sets the absolute stereochemistry of the natural product.
Keywords :
Cryptopyranmoscatone , oxa-Michael , 3 , 4 , 6-Tri-O-acetyl-d-glucal , RCM , Brown’s allylation , cross-metathesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
