Title of article
New very mild conditions for the opening of an epoxide assisted by a neighboring carbonyl group
Author/Authors
Walther، نويسنده , , Alexandre and Josien-Lefebvre، نويسنده , , Delphine and Le Drian، نويسنده , , Claude، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
2550
To page
2553
Abstract
An epoxide is opened stereo- and regio-selectively by 1,3-endo migration of a phenylthiogroup in almost neutral conditions. The thioether is then reduced to give the alcohol corresponding to the starting epoxide in an excellent yield.
Keywords
Epoxide opening , Intramolecular migration , regioselectivity , Zinc iodide , Iodine catalysis
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878135
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