Title of article
Water as efficient medium for mild decarbonylation of tertiary aldehydes
Author/Authors
Rodrigues، نويسنده , , Catarina A.B. and de Matos، نويسنده , , Marta Norton and Guerreiro، نويسنده , , Bruno M.H. and Gonçalves، نويسنده , , Ana M.L. and Romمo، نويسنده , , Carlos C. and Afonso، نويسنده , , Carlos A.M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
5
From page
2803
To page
2807
Abstract
Decarbonylation of the tertiary aldehydes 4-ethyl-4-formyl-hexanenitrile (2) and 2-methyl-2-phenylpropanal (4) promoted by dioxygen occurs at room temperature only if suspended in water probably via the sequential acyl radical–CO liberation–tertiary radical that is promoted by an ‘on water’ process originating preferentially from the corresponding tertiary hydroperoxide.
Keywords
Oxygen , Hydroperoxide , water , acyl radicals , Tertiary aldehyde , Decarbonylation
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878345
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