Title of article
A one-pot procedure for methylenating carbonyl compounds using the Nysted reagent and titanocene dichloride
Author/Authors
Haahr، نويسنده , , Adam and Rankovic، نويسنده , , Zoran and Hartley، نويسنده , , Richard C.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
3020
To page
3022
Abstract
The combination of the Nysted reagent and titanocene dichloride methylenates aldehydes and ketones to give alkenes, and in a microwave-assisted process, esters and lactones give enol ethers. The methylenating agent in this one-pot procedure is presumed to be titanocene methylidene, which is the same reactive intermediate as that generated from Tebbe, Petasis and Grubbs reagents, each of which have to be prepared before use.
Keywords
Titanium , Schrock carbene , Zinc , Microwave-assisted reactions , carbenoid
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878458
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