Title of article :
Oxidation of disulfides with Selectfluor™: concise syntheses of thiosulfonates and sulfonyl fluorides
Author/Authors :
Kirihara، نويسنده , , Masayuki and Naito، نويسنده , , Sayuri and Ishizuka، نويسنده , , Yuki and Hanai، نويسنده , , Honoka and Noguchi، نويسنده , , Takuya، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
The reaction of aromatic or benzylic disulfides with 2.5 equiv of Selectfluor™ in acetonitrile/water (10:1) at room temperature efficiently produced the corresponding thiosulfonates. On the other hand, the reaction of disulfides with 6.5 equiv of Selectfluor™ in refluxing acetonitrile/water (10:1) provided sulfonyl fluoride in high yields.
Keywords :
Selectfluor™ , disulfide , Thiosulfonate , Sulfonyl fluoride , Oxidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
