Title of article
DFT calculations induced a regiochemical outcome revision of the Diels–Alder reaction between levoglucosenone and isoprene
Author/Authors
Sarotti، نويسنده , , Ariel M. and Suلrez، نويسنده , , Alejandra G. and Spanevello، نويسنده , , Rolando A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
3116
To page
3119
Abstract
An appealing inversion in the regiochemical outcome of Diels–Alder reactions between levoglucosenone (1) and its α-bromo derivative (5) with isoprene (2) was studied computationally. Based on different DFT calculations we concluded that both reactions should display the same regioselectivity. This result was further validated experimentally.
Keywords
Levoglucosenone , DFT , Diels–Alder , Regiochemistry
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878499
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