Author/Authors :
Blond، نويسنده , , Aurélie and Moumné، نويسنده , , Roba and Bégis، نويسنده , , Guillaume and Pasco، نويسنده , , Morgane and Lecourt، نويسنده , , Thomas and Micouin، نويسنده , , Laurent، نويسنده ,
Abstract :
Rhodium(II)-catalyzed decomposition of carbene precursors grafted to the alcohol of diaminocyclopentanols promotes clean formation of a C–N bond via 1,6-insertion into an adjacent carbamate or azide. These modifications of 2-deoxystreptamine surrogates might give rise to aminoglycoside mimics where the two nitrogen atoms will be differentiated.
