Title of article
Rhodium(II) carbene-mediated modification of 2-deoxystreptamine surrogates
Author/Authors
Blond، نويسنده , , Aurélie and Moumné، نويسنده , , Roba and Bégis، نويسنده , , Guillaume and Pasco، نويسنده , , Morgane and Lecourt، نويسنده , , Thomas and Micouin، نويسنده , , Laurent، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
3201
To page
3203
Abstract
Rhodium(II)-catalyzed decomposition of carbene precursors grafted to the alcohol of diaminocyclopentanols promotes clean formation of a C–N bond via 1,6-insertion into an adjacent carbamate or azide. These modifications of 2-deoxystreptamine surrogates might give rise to aminoglycoside mimics where the two nitrogen atoms will be differentiated.
Keywords
Rhodium catalyst , Carbene , Insertion
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878538
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