Title of article
An efficient indium-mediated 2-bromoallylation of aldehydes at low temperature in aqueous DMF
Author/Authors
Kim، نويسنده , , Yu Mi and Lee، نويسنده , , Sangku and Kim، نويسنده , , Sung-Hwan and Kim، نويسنده , , Jae Nyoung، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
3240
To page
3242
Abstract
An efficient synthesis of 2-bromohomoallylic alcohols was carried out via an indium-mediated Barbier-type 2-bromoallylation of aldehydes in moderate yields. The reaction was performed at low temperature (−20 °C) in aqueous DMF in order to minimize decomposition of 2-bromoallylindium reagent to allene.
Keywords
2-Bromoallylation , Allene , Indium , Barbier reaction
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878560
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