Title of article
Chemoselective aerobic oxidation of 4-allylanisol by Fe(III) porphyrins in an aqueous system
Author/Authors
Vakuliuk، نويسنده , , Olena and Mutti، نويسنده , , Francesco G. and Lara، نويسنده , , Miguel and Gryko، نويسنده , , Daniel T. and Kroutil، نويسنده , , Wolfgang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
3555
To page
3557
Abstract
The allyl moiety of 4-allyl-anisol was oxidized in the presence of a Fe(III) porphyrin derivative to the corresponding α,β-unsaturated aldehyde in an initial oxidation step with perfect chemoselectivity. Molecular oxygen was employed as the sole environmental innocuous oxidant. The reaction was performed in an aqueous buffer/CH2Cl2 mixture using the detergent Tween 80 to homogenize the system.
Keywords
Oxidation , Porphyrin , Oxygen , Terminal alkene , aldehyde
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878693
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