Title of article
Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen
Author/Authors
Beier، نويسنده , , Petr and Past???kov?، نويسنده , , Tereza، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
4392
To page
4394
Abstract
Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols.
Keywords
Pentafluorosulfanyl group , vicarious nucleophilic substitution , hydroxylation
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879056
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