Title of article :
Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen
Author/Authors :
Beier، نويسنده , , Petr and Past???kov?، نويسنده , , Tereza، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols.
Keywords :
Pentafluorosulfanyl group , vicarious nucleophilic substitution , hydroxylation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
