Title of article :
Tin mediated Barbier type allylation in ionic liquids
Author/Authors :
Slaton، نويسنده , , Rahiem and Petrone، نويسنده , , Adam and Manchanayakage، نويسنده , , Renuka، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
The Barbier type allylation of carbonyl compounds is a useful organic transformation as the resultant homoallylic alcohols are important building blocks for many biologically active molecules. Tin mediated Barbier allylation of different carbonyl compounds in room temperature ionic liquid, [BMIM][BF4] afforded the corresponding homoallylic alcohols in good to excellent yields. The ionic liquid was successfully recycled and reused in allylation reactions.
Keywords :
Barbier reaction , Ionic liquids , organometallic reagents , Homoallylic alcohols , TIN
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters