Title of article
Ireland-Claisen rearrangement of substrates bearing chiral enol ether units
Author/Authors
Tellam، نويسنده , , James P. and Carbery، نويسنده , , David R.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
6027
To page
6029
Abstract
The Ireland-Claisen [3,3]-sigmatropic rearrangement of an allylic glycinate bearing a remote chiral enol ether has been studied. Remote exopericyclic stereocontrol is achievable in this instance. The product from this rearrangement has been progressed through a formal total synthesis of the natural antibiotic, furanomycin.
Keywords
Furanomycin , Sigmatropic , Ireland-Claisen , Amino acid , Rearrangement
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879527
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