Title of article
IrCl3 or FeCl3-catalyzed convenient synthesis of 3-hydroxyphthalates
Author/Authors
Shinohara، نويسنده , , Hiroyuki and Sonoda، نويسنده , , Motohiro and Atobe، نويسنده , , Shingo and Masuno، نويسنده , , Haruna and Ogawa، نويسنده , , Akiya، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
6238
To page
6241
Abstract
IrCl3·3H2O or FeCl3-catalyzed convenient synthesis of 3-hydroxyphthalates has been achieved by a Diels–Alder reaction of furans with dimethyl acetylenedicarboxylate, followed by ring-opening aromatization reaction of the Diels–Alder adducts, 7-oxabicyclo[2.2.1]hepta-2,5-diene derivatives. In addition, 7-azabicyclo[2.2.1]hepta-2,5-diene derivative, derived from N-Boc-pyrrole and dimethyl acetylenedicarboxylate, also converted into 3-aminophthalate derivative.
Keywords
3-Hydroxyphthalate , Iridium trichloride , Diels–Alder reaction , one-pot reaction
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879577
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