Title of article :
Reactions of 2-(trifluoromethyl)chromones with cyanoacetamides, ethyl cyanoacetate and diethyl malonate. Unexpected synthesis of benzo[c]coumarin derivatives
Author/Authors :
Sosnovskikh، نويسنده , , Vyacheslav Ya. and Safrygin، نويسنده , , Alexander V. and Anufriev، نويسنده , , Viktor A. and Eltsov، نويسنده , , Oleg S. and Iaroshenko، نويسنده , , Viktor O.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
While 2-(trifluoromethyl)chromones react with cyanoacetamides in the presence of sodium ethoxide to produce 6-(2-hydroxyaryl)-4-(trifluoromethyl)-2-oxo-1,2-dihydropyridine-3-carbonitriles, their reactions with ethyl cyanoacetate and diethyl malonate under the same conditions took an entirely different course and gave novel functionalized derivatives of 6H-benzo[c]chromen-6-one.
Keywords :
2-pyridones , Trifluoromethylated heterocycles , Chromones , Active methylene compounds
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters