Title of article :
Bidentate ligand-catalyzed enantioselective addition of RZnX to benzaldehyde
Author/Authors :
Jagtap، نويسنده , , R.S. and Joshi، نويسنده , , N.N.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
Enantioselective addition of RZnX (R = alkyl, X = Cl, OAc) was studied using chiral chelating agents, particularly metal-alkoxides. Moderate enantioselectivity was achieved in the presence of magnesium-TADDOLate using RZnOAcMg(OAc)Br as the alkylating agent.
Keywords :
organozinc , 1 , Chelating ligands , asymmetric synthesis , 2-addition
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
