Title of article :
Oxidation of thiols promoted by PhSeZnCl
Author/Authors :
Caterina Tidei، نويسنده , , Caterina and Piroddi، نويسنده , , Marta and Galli، نويسنده , , Francesco and Santi، نويسنده , , Claudio، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
The ability of PhSeZnCl 1 to catalyze the oxidation of thiols to disulfides has been evaluated and correlated to a catalytic GPx-like activity. The first evidence that vinyl phenylselenides can promote the oxidation of thiols reducing hydrogen peroxide through the formation of a selenoxide intermediate is also reported.
Keywords :
Peroxide , Oxidation , GPx mimetics , thiols , Selenolate
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters