Title of article :
Chloroacetonylation of CC double bonds promoted by manganese(III) acetate
Author/Authors :
Dengiz، نويسنده , , Cagatay and Cal??kan، نويسنده , , Ra?it and Balci، نويسنده , , Metin، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
The addition of acetylacetone to alkenes was performed using Mn(OAc)3·2H2O in the presence of HCl. The intermediate formed was trapped by chloride. Removal of one of the acetyl groups with ammonia under very mild conditions provided compounds derived from chloroacetonylation of the double bonds.
Keywords :
dihydrofuran , Acetylacetone , Manganese(III) acetate , cyclization , Chloroacetonylation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters