Author/Authors :
Trimble، نويسنده , , Laird A. and Sumarah، نويسنده , , Mark W. and Blackwell، نويسنده , , Barbara A. and Wrona، نويسنده , , Mark D. and Miller، نويسنده , , J. David، نويسنده ,
Abstract :
Two diastereomeric metabolites (16R) and (16S)-hydroxyroquefortine C were characterized from Penicillium crustosum DAOM 215343. The 16S metabolite is reported for the first time along with evidence for the absolute stereochemistry of both. The metabolites were originally detected by LC–NMR and the structures of the subsequently isolated metabolites were elucidated by HRMS and NMR.
Keywords :
Roquefortine C , Cattle toxicosis , LC–NMR , Penicillium crustosum