Title of article
Palladium-catalyzed bisfunctionalization of active alkenes by β-acetonitrile-α-allyl addition: application to the synthesis of unsymmetric 1,4-di(organo)fullerene derivatives
Author/Authors
Lu، نويسنده , , Shirong and Jin، نويسنده , , Tienan and Bao، نويسنده , , Ming and Asiri، نويسنده , , Abdullah M. and Yamamoto، نويسنده , , Yoshinori، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
1210
To page
1213
Abstract
A new, efficient palladium-catalyzed bisfunctionalization of ethylidene malononitriles by addition of acetonitrile and allyl groups is developed for the construction of all-carbon quarternary and tertiary centers simultaneously. This methodology is successfully applied to the synthesis of unsymmetric 1,4-disubstituted C60.
Keywords
?-Acetonitrile-?-allyl addition , 4-disubstituted C60 , Bisfunctionalization of active alkenes , Unsymmetric 1 , All-carbon quarternary center
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880226
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