Title of article :
Electrophilic substitution reactions using an electrogenerated ArS(ArSSAr)+ cation pool as an ArS+ equivalent
Author/Authors :
Matsumoto، نويسنده , , Kouichi and Kozuki، نويسنده , , Yuki and Ashikari، نويسنده , , Yosuke and Suga، نويسنده , , Seiji and Kashimura، نويسنده , , Shigenori and Yoshida، نويسنده , , Jun-ichi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Arylbis(arylthio)sulfonium ions (ArS(ArSSAr)+), which were generated and accumulated by the low-temperature electrolysis of diaryl disulfide (ArSSAr), were found to serve as ArS+ equivalent in electrophilic substitution reactions of aromatic compounds, enolizable ketones, enol acetates, ketene silyl acetals and allylsilanes to give the corresponding arylthiolated products.
Keywords :
Sulfenium ion , disulfide , Oxidation , Electrophilic Substitution , Electrochemistry
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
