Title of article
Palladium-catalyzed phosphinylthiolation of terminal alkynes
Author/Authors
Hoshi، نويسنده , , Nobutaka and Kashiwabara، نويسنده , , Taigo and Tanaka، نويسنده , , Masato، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
2078
To page
2081
Abstract
Phosphinylthiolation of terminal alkynes with Ph2P(O)SBu or a related compound proceeds in the presence of a palladium–PEt3 catalyst system. Activity and stereoselectivity are highly dependent on the nature of solvent, ethylbenzene, and n-hexanol (or t-amyl alcohol) being E- and Z-selective, respectively.
Keywords
alkyne , Homogeneous catalysis , PALLADIUM , Phosphinylthiolation
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880547
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